Surface Engineering of Conjugated Polybenzothiadiazoles and Integration with Cobalt Oxides for Photocatalytic Water Oxidation

Conjugated polymers feature promising structure and properties for photocatalytic water splitting. Herein, a hydrolysis strategy was demonstrated to rationally modulate the surface hydrophilicity and band structures of conjugated poly-benzothiadiazoles. High hydrophilicity not only enhances the dispersions of polymeric solids in an aqueous solution but also reduces the absorption energy of water molecules. Besides, both theoretical and experimental results reveal that a more positive valence band potential is generated, which contributes to enhancing the photocatalytic water oxidation performance. Accordingly, the surface-modified conjugated polymers show largely promoted photocatalytic water oxidation activities by deposition of cobalt oxides as cocatalysts.     

Predicting Quantum Many-Body Dynamics with Transferable Neural Net works

Advanced machine learning(ML)approaches such as transfer learning have seldom been applied to approximate quantum many-body systems.Here we demonstrate that a simple recurrent unit(SRU)based efficient and transferable sequence learning framework is capable of learning and accurately predicting the time evolution of the one-dimensional(ID)Ising model with simultaneous transverse and parallel magnetic fields,as quantitatively corroborated by relative entropy measurements between the predicted and exact state distributions.At a cost of constant computational complexity,a larger many-body state evolution is predicted in an autoregressive way from just one initial state,without any guidance or knowledge of any Hamiltonian.Our work paves the way for future applications of advanced ML methods in quantum many-body dynamics with knowledge only from a smaller system.     

采用组合引导磁场的多注二极管设计

分析了采用单一同轴磁场时强流相对论多注阴极的侧端发射问题,研究了在不同磁场内半径和多注漂移管长度情况下多注电子束的传输效率。研究发现:由于引导磁场尺寸有限,高压下多注阴极杆及多注阴极柱的电子束发射是影响多注电子束传输效率的主要因素,且该部分电子束对多注漂移管入口管壁的轰击直接影响了多注速调管的重频能力。设计了采用永磁铁和同轴磁场组合工作的强流相对论多注二极管,理论分析和模拟计算证明:基于组合磁场的多注二极管可明显减弱甚至抑制多注阴极发射球头以外的电子束发射,并且组合磁场的磁场位形和强度可满足强流相对论多注电子束的高效、稳定传输。     

白光LED用近紫外光激发的蓝绿色荧光粉Sr5(PO4)3F∶Eu2+的光谱性能及助熔剂的影响

本文采用还原氛下的高温固相法合成了荧光粉Sr5(PO4)3F∶ Eu2+并对其性能进行了表征,同时研究了助熔剂硼酸对该荧光粉的影响.结果 表明:在1200℃还原氛下制得的荧光粉Sr5(PO4)3F∶ Eu2+,激发峰位于418 nm,发射峰位于524 nm,是能与近紫外光LED相匹配的蓝绿色荧光粉.Eu2的最佳掺杂浓度为15mo1;,对应的色坐标为(0.2871,0.4036).添加助熔剂H3BO3可以使荧光粉Sr5(PO4)3F∶Eu2+的合成温度由1200℃降低到1100℃,最佳掺杂浓度为5wt;,同时可以增加荧光粉的发光强度.     

Organocatalytic Enantioselective Synthesis of Atropisomeric Aryl‐p‐Quinones: Platform Molecules for Diversity‐Oriented Synthesis of Biaryldiols

Presented here is a class of novel axially chiral aryl‐p‐quinones as platform molecules for the preparation of non‐C₂ symmetric biaryldiols. Two sets of aryl‐p‐quinone frameworks were synthesized with remarkable enantiocontrol by means of chiral phosphoric acid catalyzed enantioselective arylation of p‐quinones by central‐to‐axial chirality conversion. These aryl‐p‐quinones were then used to access a wide spectrum of highly functionalized non‐C₂ symmetric biaryldiols with excellent retention of the enantiopurity.     

适用于等熵流动的交错拉氏Godunov方法

为消除传统单元中心型Godunov方法在求解稀疏波问题时的非物理过热现象，发展一种适用于等熵流动的交错拉氏Godunov方法.主要的特征是采用速度与热力学变量交错分布的形式，避免在单元内进行速度平均，从而消除由于动量平均过程导致的动能耗散.与传统的von Neumann型交错网格方法相比，网格的边界通量由节点处的多维黎曼求解器提供，克服了多维人工粘性选取带来的困难.为减少多维黎曼求解器在求解稀疏波问题时的非物理熵增，给出稀疏波出现的合理判据，从而保证了热力学关系式的满足.数值实验表明：该方法能很好地消除稀疏波的过热现象，同时在求解激波问题时又能保持与传统单元中心型拉氏方法相同的激波捕捉能力.     

Quantum Scars in Microwave Dielec trie Photonic Graphene Billiards

Brillouin zone.The closed graphene system has proven to be the ideal model to investigate relativistic quantum chaos phenomena.The electromagnetic material photonic graphene(PG)and electronic graphene not only have the same structural symmetry,but also have the similar band structure.Thus,we consider a stadium shaped resonant cavity filled with PG to demonstrate the relativistic quantum chaos phenomenon by numerical simulation.It is interesting that the relativistic quantum scars not only are identified in the PG cavities,but also appear and disappear repeatedly.The wave vector difference between repetitive scars on the same orbit is analyzed and confirmed to follow the quantization rule.The exploration will not only demonstrate a visual simulation of relativistic quantum scars but also propose a physical system for observing valley-dependent relativistic quantum scars,which is helpful for further understanding of quantum chaos.     

紫外熔石英元件高精度低缺陷控形控性制造技术研究进展

传统的紫外熔石英元件加工方法本身会引入各类制造缺陷,需要后期加工来消除前期加工带来的缺陷,限制了熔石英元件的加工质量和加工效率。针对这些问题,课题组提出了采用磁流变、离子束、保形光顺和流体动压抛光等可控柔体加工技术提升熔石英元件的加工效果,并开展了相关研究。主要介绍了课题组在关键技术上取得的重要进展,包括亚纳米精度表面控形制造技术、纳米精度本征表面控性生成方法、熔石英元件高精度低缺陷组合工艺与设备等一系列关键技术。通过探讨关键技术及其发展现状,为未来紫外熔石英元件高精度低缺陷制造技术的发展提供参考。     

空中目标多波段红外辐射特性描述与仿真分析

针对空中目标在复杂背景下的探测需求,根据实际目标的运动特性,分析目标在飞行高度、飞行姿态角改变时的辐射特点,基于MODTRAN计算得到大气辐射和衰减数据,建立目标的三维模型、热辐射和反射模型,搭建空中目标的红外成像仿真系统.分析和仿真结果表明:在中波波段,目标尾焰的红外辐射比蒙皮强很多,在长波波段,蒙皮的红外辐射比较强,仿真图像的细节比较多,尾焰的红外辐射虽然有所减弱,红外成像效果依旧很好;相同探测条件下,由于位置越高大气越稀薄,探测器的可探测距离会变得比较远.目标红外辐射特性的分析和红外仿真系统的搭建对缩短红外探测器的研制周期和进一步确定探测器波段和系统分辨率等指标提供了参考依据.